<?xml version="1.0" encoding="UTF-8"?><metadata><idinfo><citation><citeinfo><origin>Buchanan, J.W.</origin><pubdate>2026</pubdate><title>Geochemical reanalysis of archival igneous rock pulp samples, Yukon-Tanana Upland, Alaska</title><geoform>spreadsheet</geoform><serinfo><sername>Raw Data File</sername><issue>RDF 2026-16</issue></serinfo><pubinfo><pubplace>Fairbanks, Alaska, United States</pubplace><publish>Alaska Division of Geological &amp; Geophysical Surveys</publish></pubinfo><othercit>4 p.</othercit><onlink>https://doi.org/10.14509/32120</onlink></citeinfo></citation><descript><abstract>Geochemical reanalysis of archival igneous rock pulp samples, Yukon-Tanana Upland, Alaska, Raw Data File 2026-16, presents results from the reanalysis of igneous rock samples collected by the Division of Geological and Geophysical Surveys (DGGS) during fieldwork conducted between 1997 and 2009 across the Yukon-Tanana Upland (YTU). Since 2019, the DGGS Mineral Resources Section has focused on the YTU as part of the United States Geological Survey Earth MRI program, which aims to modernize geologic mapping and improve understanding of areas with potential critical mineral resources. As part of this effort, DGGS submitted archived sample pulps stored at the DGGS Geologic Materials Center to the USGS Geology, Geophysics, and Geochemistry Science Center for modern geochemical analysis. A total of 278 pulps from previous DGGS projects, including the Salcha River-Pogo, Fortymile, Alaska Highway Corridor, Caribou Creek, and Rampart Mining District projects, were selected for reanalysis. The resulting major-, minor-, and trace-element data support interpretation of magmatic mineral systems and provide updated geochemical information that informs geologic mapping and broad tectonic interpretation across the YTU. These data and accompanying discussion are released as a DGGS Raw Data File, and all publication components are available from the DGGS website at: http://doi.org/10.14509/32120.</abstract><purpose>The purpose of this dataset is to provide updated geochemical information that strengthens Alaska's ability to evaluate critical mineral resources and understand magmatic mineral systems in the Yukon-Tanana Upland. The reanalysis of archived DGGS rock samples supports statewide mineral resource assessments, improves geologic mapping, and helps guide future exploration and land-management decisions in Alaska.</purpose><supplinf>&gt;geochemistry-download:    Digital data available through the Alaska Geochemistry database online. Download files include data, analytical methods, and detection limits.</supplinf></descript><timeperd><timeinfo><sngdate><caldate>2025</caldate></sngdate></timeinfo><current>ground condition</current></timeperd><status><progress>Complete</progress><update>None planned</update></status><spdom><bounding><westbc>-150.939531</westbc><eastbc>-141.019216</eastbc><northbc>65.256334</northbc><southbc>62.541677</southbc></bounding></spdom><keywords><theme><themekt>ISO 19115 Topic Category</themekt><themekey>geoscientificInformation</themekey></theme><theme><themekt>Alaska Division of Geological &amp; Geophysical Surveys</themekt><themekey>Analyses</themekey><themekey>Analyses and Sampling</themekey><themekey>Analytical Lab Results</themekey><themekey>Analytical Results</themekey><themekey>Base Metals</themekey><themekey>Bedrock</themekey><themekey>Bedrock Geology</themekey><themekey>Chemistry</themekey><themekey>Copper</themekey><themekey>Critical Minerals</themekey><themekey>DGGS</themekey><themekey>Earth MRI</themekey><themekey>Economic Geology</themekey><themekey>Economic Study</themekey><themekey>Exploration</themekey><themekey>Geochemical Data</themekey><themekey>Geochemical Surveys</themekey><themekey>Geochemistry</themekey><themekey>Geologic</themekey><themekey>Geology</themekey><themekey>Gold</themekey><themekey>Igneous</themekey><themekey>Igneous Rocks</themekey><themekey>Intrusion-hosted</themekey><themekey>Intrusive</themekey><themekey>Lab Methods</themekey><themekey>Major Oxides</themekey><themekey>Metallogenesis</themekey><themekey>Metals</themekey><themekey>Metamorphic</themekey><themekey>Metamorphic Minerals</themekey><themekey>Metamorphic Rocks</themekey><themekey>Methods</themekey><themekey>Mineral Assessment</themekey><themekey>Mineral Composition</themekey><themekey>Mineral Deposit Models</themekey><themekey>Mineral Development</themekey><themekey>Mineral Exploration</themekey><themekey>Mineral Resources</themekey><themekey>Mineralogy</themekey><themekey>Minerals</themekey><themekey>Minor Oxides</themekey><themekey>Platinum</themekey><themekey>Platinum Gold</themekey><themekey>Platinum Group Elements</themekey><themekey>Plutonic</themekey><themekey>Plutonic Rocks</themekey><themekey>Plutons</themekey><themekey>Precious Metals</themekey><themekey>Rare Earth Elements</themekey><themekey>Ree</themekey><themekey>Resource Assessment</themekey><themekey>Resource Information</themekey><themekey>Resources</themekey><themekey>Rocks</themekey><themekey>Sample Location</themekey><themekey>Strategic Minerals</themekey><themekey>Trace Elements</themekey><themekey>Trace Geochemical</themekey><themekey>Trace Metals</themekey></theme><place><placekt>Alaska Division of Geological &amp; Geophysical Surveys</placekt><placekey>Airs Hill</placekey><placekey>Alder Creek</placekey><placekey>American Creek</placekey><placekey>Beaver Creek</placekey><placekey>Big Lake</placekey><placekey>Boulder Creek</placekey><placekey>Buckskin Creek</placekey><placekey>Camp Creek</placekey><placekey>Cathedral Bluffs</placekey><placekey>Cathedral Rapids</placekey><placekey>Cheneathda Hill</placekey><placekey>Chicken Creek</placekey><placekey>Chisana Mining District</placekey><placekey>Chisana River</placekey><placekey>Circle Mining District</placekey><placekey>Deep Creek</placekey><placekey>Dennison Fork</placekey><placekey>Eliza Lake</placekey><placekey>Fairbanks Mining District</placekey><placekey>Fish Creek</placekey><placekey>Fortymile Mining District</placekey><placekey>Gardiner Creek</placekey><placekey>Glacier Creek</placekey><placekey>Goodpaster Mining District</placekey><placekey>Goodpaster River</placekey><placekey>Hot Springs Mining District</placekey><placekey>Indian Creek</placekey><placekey>Ingle Creek</placekey><placekey>Ladue River</placekey><placekey>Lilliwig Creek</placekey><placekey>Lost Creek</placekey><placekey>Minook Creek</placekey><placekey>Mirror Creek</placekey><placekey>Moose Creek</placekey><placekey>Northway Junction</placekey><placekey>Old Man Creek</placekey><placekey>Omega Creek</placekey><placekey>Paradise Hill</placekey><placekey>Porcupine Creek</placekey><placekey>Robertson River</placekey><placekey>Roughtop Mountain</placekey><placekey>Salcha River</placekey><placekey>Seattle Creek</placekey><placekey>Sheep Creek</placekey><placekey>Silver Creek</placekey><placekey>Sonora Creek</placekey><placekey>Stevens Creek</placekey><placekey>Stonehouse Creek</placekey><placekey>Tanana River</placekey><placekey>Tenmile Creek</placekey><placekey>Tok Mining District</placekey><placekey>Tok River</placekey><placekey>Uhler Creek</placekey><placekey>Unanimous Creek</placekey><placekey>Utah Creek</placekey><placekey>Voss Creek</placekey><placekey>Walker Fork</placekey><placekey>Willow Lake</placekey><placekey>Yarger Lake</placekey></place></keywords><accconst>This report, map, and/or dataset is available directly from the State of Alaska, Department of Natural Resources, Division of Geological &amp; Geophysical Surveys (see contact information below).</accconst><useconst>Any hard copies or published datasets utilizing these datasets shall clearly indicate their source. If the user has modified the data in any way, the user is obligated to describe the types of modifications the user has made. The user specifically agrees not to misrepresent these datasets, nor to imply that changes made by the user were approved by the State of Alaska, Department of Natural Resources, Division of Geological &amp; Geophysical Surveys. The State of Alaska makes no express or implied warranties (including warranties for merchantability and fitness) with respect to the character, functions, or capabilities of the electronic data or products or their appropriateness for any user's purposes. In no event will the State of Alaska be liable for any incidental, indirect, special, consequential, or other damages suffered by the user or any other person or entity whether from the use of the electronic services or products or any failure thereof or otherwise. In no event will the State of Alaska's liability to the Requestor or anyone else exceed the fee paid for the electronic service or product.</useconst><ptcontac><cntinfo><cntorgp><cntorg>Alaska Division of Geological &amp; Geophysical Surveys</cntorg></cntorgp><cntpos>Metadata Manager</cntpos><cntaddr><addrtype>mailing and physical</addrtype><address>3354 College Road</address><city>Fairbanks</city><state>AK</state><postal>99709-3707</postal><country>USA</country></cntaddr><cntvoice>(907)451-5020</cntvoice><cntfax>(907)451-5050</cntfax><cntemail>dggspubs@alaska.gov</cntemail><hours>8 am to 4:30 pm, Monday through Friday, except State holidays</hours><cntinst>Please view our website (https://www.dggs.alaska.gov) for the latest information on available data. Please contact us using the e-mail address provided above when possible.</cntinst></cntinfo></ptcontac><datacred>The author thanks Jaime Azain at the USGS Geology, Geophysics, and Geochemistry Science Center for help with sample coordination and discussion of data and laboratory methods. The analytical work was funded by the U.S. Geological Survey's Earth Mapping Resources Initiative (Earth MRI) analytical credits under cooperative agreement G23AC00372, and by the State of Alaska. Sample collection and shipping from the Geologic Materials Center were funded by the USGS National Geological and Geophysical Data Preservation Program (NGGDPP) under cooperative agreement G23AS00011. The views and conclusions contained in this document are those of the authors and should not be interpreted as representing the opinions or policies of the USGS. Mention of trade names or commercial products does not constitute their endorsement by the USGS.</datacred><crossref><citeinfo><origin>Solie, D.N.</origin><origin>Werdon, M.B.</origin><origin>Freeman, L.K.</origin><origin>Newberry, R.J.</origin><origin>Szumigala, D.J.</origin><origin>Speeter, G.G.</origin><origin>Elliott, B.A.</origin><pubdate>2019</pubdate><title>Bedrock-geologic map, Alaska Highway corridor, Tetlin Junction, Alaska to Canada border</title><serinfo><sername>Preliminary Interpretive Report</sername><issue>PIR 2019-3</issue></serinfo><pubinfo><pubplace>Fairbanks, Alaska, United States</pubplace><publish>Alaska Division of Geological &amp; Geophysical Surveys</publish></pubinfo><othercit>16 p., 2 sheets, scale 1:63,360</othercit><onlink>https://doi.org/10.14509/30038</onlink></citeinfo></crossref><crossref><citeinfo><origin>Szumigala, D.J.</origin><origin>Newberry, R.J.</origin><origin>Werdon, M.B.</origin><origin>Athey, J.E.</origin><origin>Flynn, R.L.</origin><origin>Clautice, K.H.</origin><pubdate>2002</pubdate><title>Bedrock geologic map of the Eagle A-1 Quadrangle, Fortymile mining district</title><serinfo><sername>Preliminary Interpretive Report</sername><issue>PIR 2002-1B</issue></serinfo><pubinfo><pubplace>Fairbanks, Alaska, United States</pubplace><publish>Alaska Division of Geological &amp; Geophysical Surveys</publish></pubinfo><othercit>1 sheet, scale 1:63,360</othercit><onlink>https://doi.org/10.14509/2864</onlink></citeinfo></crossref><crossref><citeinfo><origin>Werdon, M.B.</origin><origin>Newberry, R.J.</origin><origin>Athey, J.E.</origin><origin>Szumigala, D.J.</origin><pubdate>2004</pubdate><title>Bedrock geologic map of the Salcha River-Pogo area, Big Delta Quadrangle, Alaska</title><serinfo><sername>Report of Investigation</sername><issue>RI 2004-1B</issue></serinfo><pubinfo><pubplace>Fairbanks, Alaska, United States</pubplace><publish>Alaska Division of Geological &amp; Geophysical Surveys</publish></pubinfo><othercit>19 p., 1 sheet, scale 1:63,360</othercit><onlink>https://doi.org/10.14509/3209</onlink></citeinfo></crossref><crossref><citeinfo><origin>Werdon, M.B.</origin><origin>Solie, D.N.</origin><origin>Andrew, J.E.</origin><origin>Freeman, L.K.</origin><origin>Newberry, R.J.</origin><origin>Szumigala, D.J.</origin><origin>Elliott, B.A.</origin><pubdate>2019</pubdate><title>Bedrock-geologic map, Alaska Highway corridor, Dot Lake to Tetlin Junction, Alaska</title><serinfo><sername>Preliminary Interpretive Report</sername><issue>PIR 2019-2</issue></serinfo><pubinfo><pubplace>Fairbanks, Alaska, United States</pubplace><publish>Alaska Division of Geological &amp; Geophysical Surveys</publish></pubinfo><othercit>14 p., 2 sheets, scale 1:63,360</othercit><onlink>https://doi.org/10.14509/30037</onlink></citeinfo></crossref><crossref><citeinfo><origin>Werdon, M.B.</origin><origin>Solie, D.N.</origin><origin>Newberry, R.J.</origin><origin>Freeman, L.K.</origin><origin>Elliott, B.A.</origin><origin>Lessard, R.R.</origin><pubdate>2019</pubdate><title>Bedrock-geologic map, Alaska Highway corridor, Little Gerstle River to Dot Lake, Alaska</title><serinfo><sername>Preliminary Interpretive Report</sername><issue>PIR 2019-1</issue></serinfo><pubinfo><pubplace>Fairbanks, Alaska, United States</pubplace><publish>Alaska Division of Geological &amp; Geophysical Surveys</publish></pubinfo><othercit>12 p., 1 sheet, scale 1:63,360</othercit><onlink>https://doi.org/10.14509/30036</onlink></citeinfo></crossref></idinfo><dataqual><attracc><attraccr>This publication is a DGGS Raw Data File (RDF). Reports in the RDF series present field data and analytical results with limited or no interpretation by DGGS staff or project collaborators. The report and accompanying data have been evaluated by project staff for general readability and logical consistency but have not undergone technical peer review. Information presented in this release is subject to change.</attraccr></attracc><logic>Not applicable</logic><complete>This data release is complete.</complete><posacc><horizpa><horizpar>The location coordinates of each sample station were recorded with handheld recreational-grade GPS units, or location data were marked on paper topographic maps in the field and later digitized in GIS. GPS devices in use at that time had reported errors of approximately 30 m. GPS Selective Availability was in effect prior to 2000, and pre-2000 sites and digitized sites may have errors of up to 100 m. Sample locations were collected using the NAD27 datum and are reported here using the NAD83 datum.</horizpar></horizpa></posacc><lineage><procstep><procdesc>Sample collection - During field campaigns from 1997 to 2009, DGGS geologists collected 2â5â¯kg igneous wholeârock samples from targeted stations for geochemical analysis. The samples were selected from fresh surfaces that generally represent the exposed outcrop. The samples were geochemically analyzed soon after collection, and the returned sample pulps were stored at the DGGS Geologic Materials Center (GMC) in Anchorage, AK.</procdesc><procdate>2009</procdate></procstep><procstep><procdesc>Sample preparation - Geochemical samples were historically processed by several companies using different methods. All samples were crushed so that at least 70 percent of the material passed through a -10 mesh screen.  Either a representative 200- or 250-gram split was crushed in a chrome-steel ring mill until 85 percent passed through either a -150 or -200 mesh screen.  
For this reanalysis, samples were retrieved from the GMC and sent to the USGS, where staff used a chrome-steel ring mill to reprocess pulp samples that had passed a -150 mesh screen, reducing the sample to 85 percent passing through a -200 mesh screen, ensuring all samples met lab standards.</procdesc><procdate>2024</procdate></procstep><procstep><procdesc>Geochemistry - All samples were analyzed using GGGSC analytical packages, with analytes and methods as summarized here. Major oxides (Al2O3, CaO, Cr2O3, Fe2O3, MgO, MnO, P2O5, K2O, SiO2, Na2O, TiO2, V2O5) and loss on ignition (LOI) were determined using the WDXRF-MAJORS package, in which 0.2 to 0.5 g of sample was fused with a lithium tetraborate/lithium metaborate mixture to form a homogeneous glass disk; LOI was measured gravimetrically at 1000 C, and the prepared disks were analyzed by wavelength-dispersion X-ray fluorescence with LOI included in matrix corrections. Gold, platinum, and palladium (in ppb) were analyzed using the FA_AU-PD-PT package, in which weighed samples were mixed with flux, fused with lead oxide at 1100 C, cupelled, and the resulting bead dissolved in HCl and HNO3 prior to analysis by inductively coupled plasma optical emission spectrometry (ICP-OES). A suite of trace elements (Ag, As, Ba, Be, Bi, Cd, Ce, Cr, Co, Cs, Cu, Ga, Ge, Hf, In, La, Li, Lu, Mn, Hg, Mo, Nb, Ni, Pb, Rb, Re, Sb, Sc, Se, Sn, Sr, Ta, Te, Tb, Tl, Th, U, V, W, Y, Yb, Zn, Zr in ppm) and major elements (Al, Ca, Fe, K, Mg, Na, P, S, Ti in percent) were analyzed using the AQUA-REGIA package, in which samples were digested in a 3:1 mixture of HCl and HNO3 suitable for low-sulfide, non-organic materials, and the resulting solutions were analyzed by ICP-MS and ICP-OES. Additional trace and major elements (Ag, As, Ba, Be, Bi, B, Cd, Ce, Co, Cr, Cs, Cu, Dy, Er, Eu, Ga, Gd, Ge, Hf, Ho, In, La, Li, Lu, Mn, Mo, Nb, Nd, Ni, Pb, Pr, Rb, Sb, Sc, Sm, Sn, Sr, Ta, Tb, Th, Tl, Tm, U, V, W, Y, Yb, Zn, Zr in ppm; Al, Ca, Fe, K, Mg, P, Si, S, Ti in percent) were analyzed using the ICPOES_MS-61 package, in which samples were fused in glassy carbon crucibles with sodium peroxide (Na2O2), the resulting cake dissolved in HNO3, and the solutions analyzed by ICP-MS and ICP-OES.</procdesc><procdate>2025</procdate></procstep></lineage></dataqual><spdoinfo><direct>point</direct></spdoinfo><spref><horizsys><geograph><latres>0.0000001</latres><longres>0.0000001</longres><geogunit>decimal degrees</geogunit></geograph><geodetic><horizdn>NAD83</horizdn><ellips>GRS 80</ellips><semiaxis>6378137</semiaxis><denflat>298.257222101</denflat></geodetic></horizsys></spref><eainfo><detailed><enttyp><enttypl>geochemistry-download</enttypl><enttypd>Digital data available through the Alaska Geochemistry database online. Download files include data, analytical methods, and detection limits.</enttypd><enttypds>Alaska Division of Geological &amp; Geophysical Surveys (DGGS)</enttypds><ealname>geochemistry-download</ealname></enttyp></detailed></eainfo><distinfo><distrib><cntinfo><cntorgp><cntorg>Alaska Division of Geological &amp; Geophysical Surveys</cntorg></cntorgp><cntpos>Metadata Manager</cntpos><cntaddr><addrtype>mailing and physical</addrtype><address>3354 College Road</address><city>Fairbanks</city><state>AK</state><postal>99709-3707</postal><country>USA</country></cntaddr><cntvoice>(907)451-5020</cntvoice><cntfax>(907)451-5050</cntfax><cntemail>dggspubs@alaska.gov</cntemail><hours>8 am to 4:30 pm, Monday through Friday, except State holidays</hours><cntinst>Please view our website (https://www.dggs.alaska.gov) for the latest information on available data. Please contact us using the e-mail address provided above when possible.</cntinst></cntinfo></distrib><resdesc>RDF 2026-16</resdesc><distliab>The State of Alaska makes no expressed or implied warranties (including warranties for merchantability and fitness) with respect to the character, functions, or capabilities of the electronic data or products or their appropriateness for any user's purposes. In no event will the State of Alaska be liable for any incidental, indirect, special, consequential, or other damages suffered by the user or any other person or entity whether from the use of the electronic services or products or any failure thereof or otherwise. In no event will the State of Alaska's liability to the Requestor or anyone else exceed the fee paid for the electronic service or product.</distliab><stdorder><nondig>DGGS publications are available as free online downloads or you may purchase paper hard-copies or digital files on CD/DVD or other digital storage media by mail, phone, fax, or email from the DGGS Fairbanks office. To purchase this or other printed reports and maps, contact DGGS by phone (907-451-5020), e-mail (dggspubs@alaska.gov), or fax (907-451-5050). Payment accepted: Cash, check, money order, VISA, or MasterCard. Turnaround time is 1-2 weeks unless special arrangements are made and an express fee is paid. Shipping charge will be the actual cost of postage and will be added to the total amount due. Contact us for the exact shipping amount.</nondig><fees>Contact DGGS for current pricing</fees></stdorder><stdorder><digform><digtinfo><formname>spreadsheet</formname><formverd>20260625</formverd><formcont>table</formcont></digtinfo><digtopt><onlinopt><computer><networka><networkr>https://doi.org/10.14509/32120</networkr></networka></computer></onlinopt></digtopt></digform><fees>Free download</fees></stdorder></distinfo><metainfo><metd>20260625</metd><metc><cntinfo><cntorgp><cntorg>Alaska Division of Geological &amp; Geophysical Surveys</cntorg><cntper>Simone Montayne</cntper></cntorgp><cntpos>Metadata Manager</cntpos><cntaddr><addrtype>mailing and physical</addrtype><address>3354 College Road</address><city>Fairbanks</city><state>AK</state><postal>99709-3707</postal><country>USA</country></cntaddr><cntvoice>(907)451-5020</cntvoice><cntfax>(907)451-5050</cntfax><cntemail>dggspubs@alaska.gov</cntemail><hours>8 am to 4:30 pm, Monday through Friday, except State holidays</hours></cntinfo></metc><metstdn>FGDC Content Standard for Digital Geospatial Metadata</metstdn><metstdv>FGDC-STD-001-1998</metstdv><metuc>If the user has modified the data in any way they are obligated to describe the types of modifications they have performed in the supporting metadata file. User specifically agrees not to imply that changes they made were approved by the Alaska Department of Natural Resources or Division of Geological &amp; Geophysical Surveys.</metuc><metextns><onlink>https://dggs.alaska.gov/metadata/dggs.ext</onlink><metprof>dggs metadata extensions</metprof></metextns></metainfo></metadata>